(Ebook) Surfactants in Polymers Coatings Inks and Adhesives 1st Edition by David R Karsa ISBN 036781241X 9780367812416

(Ebook) Surfactants in Polymers Coatings Inks and Adhesives 1st Edition by David R Karsa ISBN 036781241X 9780367812416

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ISBN 10: 036781241X 
ISBN 13: 9780367812416
Author: David R Karsa

Surface active agents are used as process aids in the production of polymers--as additives to impart or modify polymer properties--and in the formulation and further processing of polymeric systems for a variety of applications. In all these uses, the surfactants are used as 'effect chemicals,' to impart specific performance characteristics or properties to the base polymer or to enhance it performance when formulated for a specific end use.This volume focuses on those surfactant areas incorporating the greatest number of supplier and user companies. Authors have been selected from leading industrial and academic laboratories around the world. It provides an introduction to the underlying chemistry and technology in these industrial areas, and at the same time, highlights important recent developments.Surfactants in Polymers, Coatings, Inks and Adhesives is a book for surfactant researchers and for manufacturers and users of surfactants. In particular, surfactant chemists, analytical chemists, environmental chemists, users of surfactant formulations in the fields of specialty chemicals, polymers, and detergents, and health and safety personnel.

(Ebook) Surfactants in Polymers Coatings Inks and Adhesives 1st Table of contents:

1 Surfactants and emulsion polymerisation: an industrial perspective
1.1 Introduction
1.2 Commercial polymers
1.3 The industrial process
1.3.1 Batch process
1.3.2 Semi-batch process
1.3.3 Continuous processes
1.4 Surfactants and polymers
1.4.1 Particle size control
1.4.2 Stabilisation of particles
1.5 Industrial applications
1.5.1 General properties
1.5.1.1 Water resistance
1.5.1.2 Foam
1.5.1.3 Filler compatibility
1.5.2 Adhesives
1.5.2.1 General adhesives
1.5.2.2 Pressure-sensitive adhesives (PSAs)
1.5.3 Construction
1.5.3.1 Caulks/sealants
1.5.3.2 Bitumen modification
1.5.4 Paper coatings
1.5.4.1 Bonded paper
1.5.5 Printing applications
1.5.6 Paint
1.5.7 Dipping
1.5.8 Non-woven fabrics
1.5.9 Textile applications
1.5.10 Synthetic rubber
1.5.11 Carpets
1.5.12 Thickeners
1.5.13 Structured particles
1.6 Choice of surfactant
1.7 Types of surfactant
1.7.1 Alkyl sulfates
1.7.2 Alkyl aryl sulfonates
1.7.3 Mono- and diester sulfosuccinates
1.7.4 Carboxylates
1.7.5 Non-ionic surfactants
1.8 Conclusion
References
2 The role of emulsifiers in the kinetics and mechanisms of emulsion polymerization
2.1 Introduction
2.1.1 Emulsion polymerization
2.1.2 Emulsifiers
2.2 Emulsifiers and emulsion polymerization
2.2.1 History
2.2.2 General remarks
2.2.3 Solubilization
2.2.4 Stabilization
2.2.5 Sustainability
2.2.6 Suitability and support
References
3 Polymerisable surfactants (surfmers) for emulsion polymerisation production
3.1 Introduction
3.2 Maleic and related surfmers
3.2.1 Synthesis and characterisation
3.2.1.1 Procedure
3.2.1.2 Characterisation
3.2.2 Applications in emulsion polymerisation
3.2.2.1 Simple hemiesters and hemiamides
3.2.2.2 Hemiester derivatives
3.2.2.3 Bifunctional derivatives of maleic surfmers
3.2.3 Commercial exploitation of maleic surfmers
3.3 Non-ionic block copolymers of oxiranes
3.3.1 Synthesis and characterisation
3.3.1.1 From commercial polyethylene glycol monomethyl ether
3.3.1.2 From a two-step ring-opening polymerisation
3.3.2 Behaviour in heterophase polymerisations
3.3.3 Commercial exploitation
3.4 Conclusion
References
4 Uses of anti-foaming agents in paints and surface coatings
4.1 Introduction
4.2 Theory of foam and foam control
4.2.1 Physicochemical fundamentals of surfaces with regard to foam and defoaming
4.2.2 Theory of foam inhibition and foam destruction
4.2.3 Mechanical defoaming
4.3 Compositions of defoamers
4.3.1 Mineral oil defoamers
4.3.2 Emulsion defoamers
4.3.3 Powder defoamers
4.3.4 Silicone-based defoamers
4.3.5 Block copolymer defoamers
4.4 Defoamers for coatings, inks and polymerisation
4.4.1 Defoamers in polymerisation
4.4.2 Defoamers in paint and ink manufacture
4.4.3 Defoamers in paint and ink application
4.4.3.1 Defoamers in water-based architectural paints and in construction materials
4.4.3.2 Re-dispersible powder paints
4.4.3.3 High-gloss paints
4.4.3.4 Aqueous wood coatings
4.4.3.5 Industrial coatings
4.4.3.6 Automotive coatings
4.4.3.7 Radiation curing systems
4.4.3.8 Inks
4.4.3.9 Defoamers in paper coating
4.5 Defoamer testing and selection
References
5 Applications of oligomeric surfactants in polymer systems
5.1 Introduction
5.2 Coatings
5.2.1 Wetting
5.2.2 Dispersing
5.2.3 Aqueous systems
5.2.4 Foaming/defoaming
5.2.5 Developments in water-based surfactants
5.2.6 Non-aqueous coatings
5.2.7 Tinting systems
5.2.7.1 Aqueous-based universal tinters
5.2.7.2 Aqueous multi-compatible tinters
5.2.7.3 Non-aqueous multi-media tinters
5.2.8 Radiation-cured coatings
5.3 Effect surfactants
5.3.1 Acety lenediols
5.3.2 Fluoro surfactants
5.3.3 Silicones
5.4 Plastic and polymer systems
5.4.1 Emulsion polymerisation
5.4.1.1 Coatings
5.4.1.2 Polishes
5.4.1.3 Adhesives
5.4.2 Inverse emulsion polymerisation
5.4.3 Siloxanes in polymer systems
5.4.4 Antistatic agents
5.4.5 Thermoset composite systems
5.4.6 Plastisols
Acknowledgements
References
6 Applications of surfactants in paints
6.1 Introduction
6.2 Surfactants as dispersant for the pigment
6.2.1 Pigment properties
6.2.2 Dispersants for waterborne formulations
6.2.3 Dispersants for solvent-borne formulations
6.3 Surfactants as emulsifiers for the binder
6.3.1 Binders made by emulsion polymerization
6.3.2 Post-emulsified binders
6.4 Surfactants as wetting agents
6.4.1 Effect of the critical surface tension
6.4.2 The wetting agent
6.5 Surfactants as antifoaming agents
6.6 Rheology control agents
6.7 Effect of surfactants in the dry film
References
7 Surfactant-waterborne polymer interactions in coating applications
7.1 Introduction
7.2 Interaction in dilute solutions
7.2.1 General aspects
7.2.2 Non-ionic polymers and non-ionic surfactants
7.2.3 Non-ionic polymers and ionic surfactants
7.2.4 Oppositely charged polymers and surfactants
7.2.5 Hydrophobically modified polymers and non-ionic and ionic surfactants
7.3 Interaction in concentrated solutions
7.4 Interaction at interfaces
7.4.1 Surfactant adsorption
7.4.2 Polymer adsorption
7.5 Competitive adsorption of polymers and surfactants on surfaces
7.6 Conclusion
References
8 Surfactants in ink-jet inks
8.1 Introduction
8.2 Properties of surfactants
8.3 Dynamic surface tension
8.4 Micellization
8.5 The theory of surfactant-induced wetting
8.6 Ink-jet printing
8.7 Ink formulations
8.8 Selected groups of performance surfactants
8.8.1 Gemini surfactants
8.8.2 Fluorinated surfactants
8.8.3 Polymerizable surfactants
8.8.4 Polymeric surfactants
8.8.5 Silicone surfactants
8.8.6 Alkyloxypropylamines
8.8.7 Phospholipids
8.8.8 2-Alkylimidazolines
8.8.9 Polyamines
Notes
Acknowledgements
References
9 Process aids and additives for latexes and thermoplastics
9.1 PVC plastisols
9.1.1 Plastisol manufacturing processes
9.1.1.1 Spread coating
9.1.1.2 Reverse roll coating
9.1.1.3 Screen coating
9.1.1.4 Coil coating
9.1.1.5 Spraying
9.1.1.6 Dipping
9.1.1.7 Moulding
9.1.1.8 Mechanical foaming
9.1.2 Plastisol additives
9.1.2.1 Viscosity modifiers
9.1.2.2 Antistatic agents
9.1.3 Wetting and dispersing agents
9.1.4 Foaming agents
9.1.5 Heat stabilisers
9.1.5.1 Organotin stabilisers
9.1.5.2 Liquid mixed metal soap stabilisers
9.1.5.3 Kicker stabilisers
9.1.5.4 Solid and paste stabilisers
9.1.6 Epoxy co-stabilisers
9.1.7 Textile bonding agents
9.1.8 Microbiocides
9.1.9 Deaeration agents
9.2 Foaming agents for water-based polymers
9.2.1 Foamed latex carpet backings
9.2.1.1 Foaming agents
9.2.1.2 Typical no-gel compound formulations
9.2.2 Foamed anchor coats
9.2.2.1 Wetting agents
9.2.2.2 Surfactants to reduce process odours from ‘cure’ chemicals
9.2.3 Foamed polymer coatings for curtaining and upholstery
9.2.3.1 Foam production
9.2.3.2 Foam application
9.2.3.3 Typical formulations
9.3 Foam control agents
9.3.1 Foam formation
9.3.2 Foam control using a defoamer
9.3.3 Foam control using an antifoam
9.3.4 The composition of foam control agents
Acknowledgements
10 The role of surfactants in phosphate conversion coatings
10.1 Introduction
10.1.1 Chemistry of phosphating
10.1.2 Applications
10.1.3 Developments and implications
10.2 Surfactants in phosphating
10.3 Effect of surfactants on phosphate film epitaxy
10.4 Effect of long-chain amines on phosphate coating weight
10.5 Effect of long-chain amines on the properties of phosphate coatings
10.6 Effect of long-chain amines on the corrosion resistance of phosphate coatings
10.7 Conclusion
Acknowledgements
References

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Tags: David R Karsa, Surfactants, Polymers