(Ebook) Supramolecular and Self Assembled Metal Containing Materials 1st Edition by Alaa S Abd El Aziz, Charles E Carraher, Charles U Pittman, Martel Zeldin ISBN 9780470251447 0470251441

(Ebook) Supramolecular and Self Assembled Metal Containing Materials 1st Edition by Alaa S Abd El Aziz, Charles E Carraher, Charles U Pittman, Martel Zeldin ISBN 9780470251447 0470251441

(Ebook) Supramolecular and Self Assembled Metal Containing Materials 1st Edition by Alaa S Abd El Aziz, Charles E Carraher, Charles U Pittman, Martel Zeldin - Ebook PDF Instant Download/Delivery: 9780470251447 ,0470251441
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ISBN 10: 0470251441
ISBN 13: 9780470251447
Author: Alaa S Abd El Aziz, Charles E Carraher, Charles U Pittman, Martel Zeldin

(Ebook) Supramolecular and Self Assembled Metal Containing Materials 1st Edition Table of contents:

1. Supramolecular Structures and Functions with Inorganic Building Blocks

• Hybrid Lipid Thin Films

• Layer-by-Layer Assemblies

• Structure Transcription

• Functional Mesoporous Hybrids

• References

2. Self-Assembly of Hydrophilic Polyoxometalate Macroanions in Dilute Solutions

• Introduction

• Solution Behavior of POM Macroions: Soluble but Still Aggregate

• Characterization of the Supramolecular Structures

• Controlling the Blackberry Formation and Blackberry Size by Changing Solvent Quality

• Counterion Association around Discrete POM Macroions

• Counterion Condensation around Blackberries

• Soft Nature of the Blackberries—Effect of Additional Hydrogen Bonding

• Weak Electrolyte Type POMs

• Effect of Additional Electrolytes

• Kinetic Process of Blackberry Formation

• Cation Transport over the Anionic Blackberry Membrane

• Macroions in Solution: An Important Linkage among Simple Ions, Polymers, Colloids, and Biosystems

• References

3. Supramolecular Structures and Polyoxometalates

• Supramolecular Features of Polyoxometalate-Supported Transition-Metal Complexes

• Polyoxometalate Crown Ether Complexes with Supramolecular Cations

• Supramolecular Water Clusters Associated with Polyoxometalates

• Concluding Remarks

• Acknowledgements

• References

4. Supramolecular Coordination Networks Employing Sulfonate and Phosphonate Linkers: From Layers to Open Structures

• Introduction

• The Sulfonate Group as a Ligand

• Layered Metal Sulfonates

• Nonlayered Metal Sulfonates

  • Dynamic and Crystalline Metal Sulfonate Frameworks

  • Hydrogen Bonded Second Sphere Coordination Networks

• Metal Phosphonates

• Conclusion

• References

5. Transition-Metal-Based Linear Chain Compounds

• Introduction

  • Linear Chains of Chromium

  • Linear Metal Chains of Cobalt

  • Linear Chains of Copper

  • Linear Chains of Nickel

  • Linear Chains of Palladium

  • Linear Chain Compounds of Rhodium

  • Linear Chain of Iridium

  • The Platinum Blues

• Concluding Remarks

• References

6. Boronate-Linked Materials: Ranging from Amorphous Assemblies to Highly Structured Networks

• Introduction and Scope

• Supramolecular Boronate Assemblies

  • "Novel" Phenyl-Boron-Phenyl Sandwich Supramolecular Assembly

  • Coordination-Based Macrocyclic Assemblies

  • Coordination-Based Linear Assemblies

• Covalently Linked Boronate Assemblies

  • Covalently Linked Macrocyclic and Cage Assemblies

  • Covalently Linked Linear Assemblies

  • Covalently Linked Network Assemblies

• Summary and Outlook

• References

7. Mixed-Metal Supramolecular Complexes Coupling Polyazine Light Absorbers and Reactive Metal Centers

• Introduction

  • Light Absorption

    • Ruthenium Charge Transfer Light Absorbers

    • Osmium Charge Transfer Light Absorbers

  • Solar Water Splitting

  • Supramolecular Charge Transfer Complexes

  • Cyclic Voltammetry of Charge Transfer Light Absorbers

    • Various Redox, Spectroscopic, and Photophysical Properties of Ru(II)-Rh(III) and Ru(II)-Pt(II) Complexes

  • Photoinitiated Electron Collection

  • DNA Binding and Photocleavage Agents

  • Ru(II)-Pd(II) Complexes and Polyazine Bridging Ligands

• Conclusions

• References

8. Supramolecular Hybrid Materials—Integrating Functionality with Sensing

• Introduction

• Enhanced Coordination by Preorganization: Surface Chelate Effect and Signaling

• Enhanced Signaling by Preorganization

• Assembly-Disassembly

• Selectivity by Polarity and Size: Biomimetic Signaling

• Switching, Gating, and Signaling

• Conclusions

• References

9. Molecular Recognition Process between Nucleobases and Metal-Oxalato Frameworks

• Molecular Recognition

• Nucleobases

• Oxalate

• Metal-Oxalato-Nucleobase Extended Systems

• Other Metal-Nucleobase 1D Extended Systems

• Hybrid Systems Based on Metal-Oxalato and Protonated Nucleobases

• References

10. Crystal Engineering of Coordination Polymers

• Introduction

• Synthetic Approaches

  • The Node-and-Spacer Paradigm

    • Bridging Ligands

    • Oligonuclear Complexes as Nodes

      • Alkoxo-Bridged Binuclear Copper(II) Complexes

      • Homobinuclear Complexes with Compartmental Ligands

      • Heterobinuclear and Heterotrimetallic Complexes

  • Flexible Ligand Approach: Polycarboxylates as Anionic Linkers

    • Dicarboxylates

    • Synthetic Condition Influences

    • Co-ligands

    • Ligand Adaptation

  • The Building-Block Approach

    • Oxalato-Bridged Coordination Polymers

    • Cyano-Bridged Coordination Polymers

• Conclusions and Perspectives

• References

Index

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Tags: Alaa S Abd El Aziz, Charles E Carraher, Charles U Pittman, Martel Zeldin, Self Assembled, Supramolecular