(Ebook) Science and technology of rubber 3rd Edition by James E Mark, Burak Erman, Frederick Eirich ISBN 9780124647862 0124647863

(Ebook) Science and technology of rubber 3rd Edition by James E Mark, Burak Erman, Frederick Eirich ISBN 9780124647862 0124647863

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ISBN 10: 0124647863
ISBN 13: 9780124647862
Author: James E Mark, Burak Erman, Frederick Eirich

The 3rd edition of The Science and Technology of Rubber provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing.

Many advances have been made in polymer and elastomers research over the past ten years since the 2nd edition was published. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling.

· Explores new applications of rubber within the tire industry, from new filler materials to “green tires” (a tire that has yet to undergo curing and vulcanization).
· 30% of the material has been revised from the previous edition with the addition of 20% new material, including a chapter on the environment.
· A mixture of theory, experiments, and practical procedures will offer value to students, practitioners, and research & development departments in industry.

(Ebook) Science and technology of rubber 3rd Edition Table of contents:

1. Rubber Elasticity: Basic Concepts and Behavior

I. INTRODUCTION

II. ELASTICITY OF A SINGLE MOLECULE

III. ELASTICITY OF A THREE-DIMENSIONAL NETWORK OF POLYMER MOLECULES

IV. COMPARISON WITH EXPERIMENT

V. CONTINUUM THEORY OF RUBBER ELASTICITY

VI. SECOND-ORDER STRESSES

VII. ELASTIC BEHAVIOR UNDER SMALL DEFORMATIONS

VIII. SOME UNSOLVED PROBLEMS IN RUBBER ELASTICITY

ACKNOWLEDGMENTS

REFERENCES

2. Polymerization: Elastomer Synthesis

I. INTRODUCTION

II. CLASSIFICATION OF POLYMERIZATION REACTIONS AND KINETIC CONSIDERATIONS

III. Polyaddition/Polycondensation

IV. CHAIN POLYMERIZATION BY FREE RADICAL MECHANISM

V. EMULSION POLYMERIZATION

VI. COPOLYMERIZATION

VII. Chain Polymerization by Cationic Mechanism

VIII. CHAIN POLYMERIZATION BY ANIONIC MECHANISM

IX. STEREOSPECIFIC CHAIN POLYMERIZATION AND COPOLYMERIZATION BY COORDINATION CATALYSTS

X. GRAFT AND BLOCK COPOLYMERIZATION

REFERENCES

3. Structure Characterization in the Science and Technology of Elastomers

I. INTRODUCTION

II. CHEMICAL COMPOSITION

III. SEQUENCE DISTRIBUTION OF REPEAT UNITS

IV. CHAIN ARCHITECTURE

V. GLASS TRANSITION AND SECONDARY RELAXATION PROCESSES

VI. MORPHOLOGY

ACKNOWLEDGMENTS

REFERENCES

4. The Molecular Basis of Rubberlike Elasticity

I. INTRODUCTION

II. STRUCTURE OF A TYPICAL NETWORK

III. ELEMENTARY MOLECULAR THEORIES

IV. MORE ADVANCED MOLECULAR THEORIES

V. PHENOMENOLOGICAL THEORIES AND MOLECULAR STRUCTURE

VI. SWELLING OF NETWORKS AND RESPONSIVE GELS

VII. ENTHALPIC AND ENTROPIC CONTRIBUTIONS TO RUBBER ELASTICITY: FORCE-TEMPERATURE RELATIONS

VIII. DIRECT DETERMINATION OF MOLECULAR DIMENSIONS

IX. SINGLE-MOLECULE ELASTICITY

REFERENCES

5. The Viscoelastic Behavior of Rubber

I. INTRODUCTION

II. DEFINITIONS OF MEASURED QUANTITIES, J(t), G(t), AND G*(ω), AND SPECTRA L(log λ) AND H(log τ)

III. THE GLASS TEMPERATURE

IV. VOLUME CHANGES DURING CURING

V. VISCOELASTIC BEHAVIOR ABOVE Tg

VI. VISCOELASTIC BEHAVIOR OF OTHER MODEL ELASTOMERS

VII. THE CALCULATION OF THE TEAR ENERGY OF ELASTOMERS FROM THEIR VISCOELASTIC BEHAVIOR

VIII. THEORETICAL INTERPRETATION OF VISCOELASTIC MECHANISMS AND ANOMALIES

IX. APPENDIX: NOMENCLATURE

REFERENCES

6. Rheological Behavior and Processing of Unvulcanized Rubber

I. INTRODUCTION

II. BASIC CONCEPTS OF MECHANICS

III. RHEOLOGICAL PROPERTIES

IV. BOUNDARY CONDITIONS

V. MECHANOCHEMICAL BEHAVIOR

VI. RHEOLOGICAL MEASUREMENTS

VII. PROCESSING TECHNOLOGY

VIII. ENGINEERING ANALYSIS OF PROCESSING

REFERENCES

7. Vulcanization

I. INTRODUCTION

II. DEFINITION OF VULCANIZATION

III. EFFECTS OF VULCANIZATION ON VULCANIZATE PROPERTIES

IV. CHARACTERIZATION OF THE VULCANIZATION PROCESS

V. VULCANIZATION BY SULFUR WITHOUT ACCELERATOR

VI. ACCELERATED-SULFUR VULCANIZATION

VII. VULCANIZATION BY PHENOLIC CURATIVES, BENZOQUINONE DERIVATIVES, OR BISMALEIMIDES

VIII. VULCANIZATION BY THE ACTION OF METAL OXIDES

IX. VULCANIZATION BY THE ACTION OF ORGANIC PEROXIDES

X. DYNAMIC VULCANIZATION

REFERENCES

8. Reinforcement of Elastomers by Particulate Fillers

I. INTRODUCTION

II. PREPARATION OF FILLERS

III. MORPHOLOGICAL AND PHYSICOCHEMICAL CHARACTERIZATION OF FILLERS

IV. THE MIX: A NANOCOMPOSITE OF ELASTOMER AND FILLER

V. MECHANICAL PROPERTIES OF FILLED RUBBERS

REFERENCES

9. The Science of Rubber Compounding

I. INTRODUCTION

II. POLYMERS

III. FILLER SYSTEMS

IV. STABILIZER SYSTEMS

V. VULCANIZATION SYSTEM

VI. SPECIAL COMPOUNDING INGREDIENTS

VII. COMPOUND DEVELOPMENT

VIII. COMPOUND PREPARATION

IX. ENVIRONMENTAL REQUIREMENTS IN COMPOUNDING

X. SUMMARY

REFERENCES

10. Strength of Elastomers

I. INTRODUCTION

II. INITIATION OF FRACTURE

III. THRESHOLD STRENGTHS AND EXTENSIBILITIES

IV. FRACTURE UNDER MULTIAXIAL STRESSES

V. CRACK PROPAGATION

VI. TENSILE RUPTURE

VII. REPEATED STRESSING: MECHANICAL FATIGUE

VIII. SURFACE CRACKING BY OZONE

IX. ABRASIVE WEAR

ACKNOWLEDGMENTS

REFERENCES

11. The Chemical Modification of Polymers

I. INTRODUCTION

II. CHEMICAL MODIFICATION OF POLYMERS WITHIN BACKBONE AND CHAIN ENDS

III. ESTERIFICATION, ETHERIFICATION, AND HYDROLYSIS OF POLYMERS

IV. THE HYDROGENATION OF POLYMERS

V. DEHALOGENATION, ELIMINATION, AND HALOGENATION REACTIONS IN POLYMERS

VI. OTHER ADDITION REACTIONS TO DOUBLE BONDS

VII. OXIDATION REACTIONS OF POLYMERS

VIII. FUNCTIONALIZATION OF POLYMERS

IX. MISCELLANEOUS CHEMICAL REACTIONS OF POLYMERS

X. BLOCK AND GRAFT COPOLYMERIZATION

REFERENCES

12. Elastomer Blends

I. INTRODUCTION

II. MISCIBLE ELASTOMER BLENDS

III. IMMISCIBLE ELASTOMER BLENDS

IV. CONCLUSION

V. APPENDIX 1: ACRONYMS FOR COMMON ELASTOMERS

REFERENCES

13. Thermoplastic Elastomers

I. INTRODUCTION

II. SYNTHESIS OF THERMOPLASTIC ELASTOMERS

III. MORPHOLOGY OF THERMOPLASTIC ELASTOMERS

IV. PROPERTIES AND EFFECT OF STRUCTURE

V. THERMODYNAMICS OF PHASE SEPARATION

VI. THERMOPLASTIC ELASTOMERS AT SURFACES

VII. RHEOLOGY AND PROCESSING

VIII. APPLICATIONS

REFERENCES

14. Tire Engineering

I. INTRODUCTION

II. TIRE TYPES AND PERFORMANCE

III. BASIC TIRE DESIGN

IV. TIRE ENGINEERING

V. TIRE MATERIALS

VI. TIRE TESTING

VII. TIRE MANUFACTURING

VIII. SUMMARY

REFERENCES

15. Recycling of Rubbers

I. INTRODUCTION

II. RETREADING OF TIRE

III. RECYCLING OF RUBBER VULCANIZATES

IV. USE OF RECYCLED RUBBER

V. PYROLYSIS AND INCINERATION OF RUBBER

VI. CONCLUDING REMARKS

ACKNOWLEDGMENTS

REFERENCES

Index

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Tags: James E Mark, Burak Erman, Frederick Eirich, Science, technology, rubber