(Ebook) Progress in Inorganic Chemistry 1st Edition by Kenneth D Karlin ISBN 0470395478 9780470395479

(Ebook) Progress in Inorganic Chemistry 1st Edition by Kenneth D Karlin ISBN 0470395478 9780470395479

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ISBN 10: 0470395478 
ISBN 13: 9780470395479
Author: Kenneth D Karlin 

This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 59 continues to report recent advances with a significant, up-to-date selection of contributions by internationally-recognized researchers. The chapters of this volume are devoted to the following topics: • Iron Catalysis in Synthetic Chemistry • A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive Sites • Selective Binding of Zn2+ Complexes to Non-Canonical Thymine or Uracil in DNA or RNA. • Progress Toward the Electrocatalytic Production of Liquid Fuels from Carbon Dioxide • Monomeric Dinitrosyl Iron Complexes: Synthesis and Reactivity • Interactions of Nitrosoalkanes/arenes, Nitrosamines, Nitrosothiols, and Alkyl Nitrites with Metals • Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging Oxidative Transformations

(Ebook) Progress in Inorganic Chemistry 1st Table of contents:

Chapter 1: Iron Catalysis in Synthetic Chemistry
I. Introduction
II. Addition Reactions
III. The C–C Bond Formations VIA C–H Functionalization
IV. The C–H Bond Oxidation
V. Cross-Coupling Reactions
VI. Direct C–N Bond Formation VIA C–H Oxidation
VII. Iron-Catalyzed Amination
VIII. Sulfoxidations and Synthesis of Sulfoximines, Sulfimides, and Sulfoximides
IX. Reduction Reactions
X. Trifluoromethylation
XI. Conclusion
Acknowledgments
Abbreviations
References
Chapter 2: A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive Sites
I. Introduction
II. Photodynamic Therapy
III. Platinum and Rhodium Centers as Bioactive Sites
IV. Supramolecular Complexes as DNA Photomodification Agents
V. Conclusions
Acknowledgments
Abbreviations
References
Chapter 3: Selective Binding of Zn2+ Complexes to Non-Canonical Thymine or Uracil in DNA or RNA
I. Introduction
II. Interaction OF Zn2+ Macrocyclic Complexes with Nucleosides and Single-Stranded Oligonucleotides
III. Interaction of Zn2+ Macrocyclic Complexes with Double-Stranded Nucleic Acids
IV. Recognition of Thymine or Uracil Bulges and Other Non-Canonical Structures
V. Energetic Factors in DNA Binding: Toward More Selective Zn2+ Recognition Agents
VI. Summary
Acknowledgments
Abbreviations
References
Chapter 4: Progress Toward the Electrocatalytic Production of Liquid Fuels from Carbon Dioxide
I. Introduction
II. Electrocatalytic Reduction of CO2
III. Metal Complexes Supported by Macrocycles
IV. Metal Polypyridyl Complexes
V. Metal Phosphine Complexes
VI. Future Development of CO2 Reduction Catalysts: Nature as Inspiration
VII. Summary and Conclusions
Acknowledgments
Abbreviations
References
Chapter 5: Monomeric Dinitrosyl Iron Complexes: Synthesis and Reactivity
I. Introduction
II. Anionic Dinitrosyl Iron Complexes
III. Cationic Dinitrosyl Iron Complexes
IV. Neutral Dinitrosyl Iron Complexes
V. Summary and Perspective
Acknowledgments
Abbreviations
References
Chapter 6: Interactions of Nitrosoalkanes/arenes, Nitrosamines, Nitrosothiols, and Alkyl Nitrites with Metals
I. Introduction
II. Nitrosoalkanes and Nitrosoarenes
III. Nitrosamines
IV. Nitrosothiols
V. Alkyl Nitrites
VI. Outlook
Acknowledgments
Abbreviations
References
Chapter 7: Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging Oxidative Transformations
I. Aminopyridine Iron Complexes as Molecular Catalysts for Hydrocarbon Oxidations
II. Aminopyridine Manganese Complexes as Molecular Catalysts For Hydrocarbon Oxidations
III. Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Water Oxidation
IV. Conclusion
Acknowledgments
Abbreviations
References
Subject Index
Cumulative Index

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