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ISBN 10: 1118935667
ISBN 13: 9781118935668
Author: Richard Tilley
Researchers and graduate students in materials science, solid state chemistry, physics and geology.
Applied research laboratories involved in energy research, optoelectronics and electronics, magnetics and display technology.
1 The ABX3 Perovskite Structure
1.1 Perovskites
1.2 The Cubic Perovskite Structure: SrTiO3
1.3 The Goldschmidt Tolerance Factor
1.4 ABX3 Perovskite Structure Variants
1.5 Cation Displacement: BaTiO3 as an Example
1.6 Jahn–Teller Octahedral Distortion: KCuF3 as an Example
1.7 Octahedral Tilting
1.8 Symmetry Relationships
1.9 Hybrid Organic–Inorganic Perovskites
1.10 Antiperovskites
1.11 Structure-Field Maps
1.12 Theoretical Calculations
References
Further Reading
2 ABX3–Related Structures
2.1 Double Perovskites and Related Ordered Structures
2.2 Anion Substituted Perovskites
2.3 A-Site-Deficient Perovskite Structures
2.4 Anion-Deficient Phases Containing Tetrahedra
2.5 Anion-Deficient Phases Containing Square Pyramids
2.6 Point Defects, Microdomains and Modulated Phases
Further Reading
3 Hexagonal Perovskite–Related Structures
3.1 The BaNiO3 Structure
3.2 BaNiO3-Related Phases Containing Trigonal Prisms
3.3 Perovskites with Mixed Hexagonal/Cubic Packing: Nomenclature
3.4 Perovskites with Mixed Hexagonal/Cubic Packing: Stacking Sequences
3.5 Hexagonal Perovskites with chq and cph Stacking
3.6 Hexagonal Perovskites with cphh Stacking
3.7 Anion-Deficient Phases Containing BaO2 (c′) Layers
3.8 Anion-Deficient Phases with BaOX Layers
3.9 Sr4Mn3O10 and Ba6Mn5O16
3.10 Temperature and Pressure Variation
Reference
Further Reading
4 Modular Structures
4.1 K2NiF4 (A2BX4) and Ruddlesden–Popper Phases
4.2 The Nd2CuO4 (T′) and T* Structures
4.3 Dion–Jacobson and Related Phases
4.4 Aurivillius Phases
4.5 The Ca2Nb2O7-Related Phases
4.6 Cuprate Superconductors and Related Phases
4.7 Composition Variation
4.8 Intercalation and Exfoliation
Further Reading
5 Diffusion and Ionic Conductivity
5.1 Diffusion
5.2 Ionic Conductivity
5.3 Proton Conductivity
5.4 Oxygen Pressure Dependence and Electronic Conductivity
5.5 Oxide Ion Mixed Conductors
5.6 Proton Mixed Conductors
5.7 Solid Oxide Fuel Cells
References
Further Reading
6 Dielectric Properties
6.1 Insulating Perovskites
6.2 Dielectric Perovskites
6.3 Ferroelectric/Piezoelectric Perovskites
6.4 The Development of Ferroelectric/Piezoelectric Ceramic Bodies
6.5 Antiferroelectrics
6.6 Ferrielectrics
6.7 Relaxor Ferroelectrics
6.8 Improper Ferroelectricity
6.9 Doping and Modification of Properties
6.10 Nanoparticles and Thin Films
References
Further Reading
7 Magnetic Properties
7.1 Magnetism in Perovskites
7.2 Paramagnetic Perovskites
7.3 Antiferromagnetic Perovskites
7.4 Ferromagnetic Perovskites
7.5 Ferrimagnetic Perovskites
7.6 Spin Glass Behaviour
7.7 Canted Spins and Other Magnetic Ordering
7.8 Thin Films
7.9 Nanoparticles
7.10 Multiferroic Perovskites
References
Further Reading
8 Electronic Conductivity
8.1 Perovskite Band Structure: Metallic Perovskites
8.2 Metal–Insulator Transitions
8.3 Perovskite Superconductors
8.4 Cuprate High-Temperature Superconductors
8.5 Spin Polarisation and Half-Metals
8.6 Charge Ordering and Orbital Ordering
8.7 Magnetoresistance
8.8 Semiconductivity in Perovskites
8.9 Thin Films and Surface Conductivity
References
Further Reading
9 Thermal and Optical Properties
9.1 Thermal Expansion
9.2 Thermoelectric Properties
9.3 The Magnetocaloric Effect
9.4 The Pyroelectric and Electrocaloric Effect
9.5 Transparency
9.6 Electrochromic Films
9.7 Electro-optic Properties
9.8 Perovskite Solar Cells
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Tags: Perovskites, Structure Property, Relationships, Richard Tilley